Ro
 

En
 My mail@phys
>> Research projects > CSSDT 18.80013.16.03.03/It
or

Gheorghe Medinschi
19.04.1951 - 26.01.2019


Contacts:
Institute of Applied Physics
5 Academiei str.
Chisinau, MD-2028
MOLDOVA (Rep. of)
phone: +(373) 22 738150
fax: +(373) 22 738149
email: [javascript protected email address]

Project CSSDT 18.80013.16.03.03/It New Hybrid Inorganic/Organic Materials Based on Optoelectronically Active Triimidazole Ligand

Type :Bilateral project SCSTD (ASM) - the National Research Council (CNR, Italy) # 18.80013.16.03.03/It
Head :Marina Fonari, Ph.D.
Duration :2018 - 2019
Division(s) :Laboratory of Physical Methods of Solid State Investigation “Tadeusz Malinowski”

The present project will tackle first coordination of cyclic triimidazole to Cu(I) halides which are known to give a variety of structural formats by simply changing reaction conditions. Different synthetic procedures will be evaluated including traditional solution reactions (with different solvents, molar ratios, etc.) together with solvothermal and mecanochemical syntheses. Furthermore, due to the copper d10 electronic configuration, the emissive properties of the obtained materials could be also affected by external stimuli, thus their thermochromic, vapochromic and mechanochromic behaviour will also be investigated. Subsequently, the chemical modification of cyclic triimidazole with introduction of functional groups such as pyridine or bypiridine, is also envisaged in order to provide additional linkers useful for the synthesis of CPs or MOF. Beside Cu(I), the project aims at developing synthetic routes for the preparation of hybrid organic/inorganic materials based on transition metals such as Zn(II), Cd(II) and Ru(II) by using as organic ligand cyclic triimidazole or its functionalized derivatives. The syntheses will be coupled with a comprehensive evaluation of the spectroscopical and structural properties of the new compounds, together with a rationalization of the results by computational techniques.

Marina Fonari
Ph.D., assoc. prof.
project head (RM)
cab.: 145
phone: +(373) 22 738154 
e-mail: [javascript protected email address]
www: http://www.phys.asm.md/en/personalpages/mfonari
 
Victor Kravtsov
Ph.D., assoc. prof.
leading scientific researcher
cab.: 108
phone:+(373) 22 725887
email: [javascript protected email address]
www: http://www.phys.asm.md/en/personalpages/vkravtsov      
 
Lilia Croitor 
Ph.D.
leading scientific researcher
cab.: 144
pfone: +(373) 22 738154 
e-mail: [javascript protected email address]
www: http://www.phys.asm.md/en/personalpages/lcroitor
 
Diana Kishka
Ph.D.
scientific researcher
cab.: 105
phone: +(373) 22 738154
e-mail: <email chisca_andreea@yahoo.com>
www: http://www.phys.asm.md/en/personalpages/dchisca
 
Victor Bold
    
scientific researcher
cab.: 144
phone: +(373) 22 738154
e-mail: [javascript protected email address]
www: http://www.phys.asm.md/en/personalpages/vbold
Elena Melnic
    
scientific researcher
cab.: 144
phone: +(373) 22 738154
e-mail: [javascript protected email address]
www: http://www.phys.asm.md/en/personalpages/emelnic
report a bug close

Report a bug